3,5-Dimethyl-2,6-diphenyl-3,4,5,6-tetrahydro-2H-pyran-4-one

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3,5-Dimethyl-2,6-diphenyl-3,4,5,6-tetra­hydro-2H-pyran-4-one

The mol-ecular structure of the title compound, C(19)H(20)O(2), reveals a slightly distorted chair conformation for the tetra-hydro-pyran ring with the two methyl and two phenyl substituents in equatorial positions.

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5,6-Dimethyl-4-phenyl-2H-pyran-2-one

In the title compound, C(13)H(12)O(2), the dihedral angle between the pyran-one and phenyl rings is 57.55 (9)°. In the crystal, the mol-ecules are linked by π-π stacking inter-actions between the parallel pyran-one rings of neighboring mol-ecules with distances of 3.5778 (11) Å and 3.3871 (11) Å between the planes. C-H⋯O interactions also occur.

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6-Hydroxy­methyl-4-meth­oxy-2H-pyran-2-one (Opuntiol)

The title compound, C(7)H(8)O(4), isolated from Opuntia dillenii Haw (Cacta-ceae), is almost planar [maximum deviation of 0.027 (2) Å] except for the H atoms of the methylene and methyl groups. The crystal packing is stabilized by C-H⋯O and O-H⋯O inter-molecular hydrogen bonds, resulting in the formation of a three-dimensional network.

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(S)-6-{[(S)-2,2-Dimethyl-1,3-dioxolan-4-yl]meth­yl}-5,5-difluoro-5,6-dihydro-2H-pyran-2-one

The title compound, C(11)H(14)F(2)O(4), is a γ,γ-gem-difluorinated α,β-unsaturated δ-lactone. The dioxolane five-membered ring and the lactone ring adopt half-chair conformations. There are two inter-molecular C-H⋯O inter-actions involving the carbonyl group as an acceptor which stabilize the crystal structure.

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Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)

In the title compound, [Ni(C(8)H(7)O(4))(2){(CH(3))(2)SO}(2)], the Ni(II) atom is located on a crystallographic centre of symmetry and has a distorted octa-hedral coordination geometry of type MO(6). The bidentate dehydro-acetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809001792